Ed Westwick & Leighton Meester's "Gossip Girl" Pair-Up

Putting together a new CW episode, Leighton Meester and Ed Westwick were side-by-side on the New York City set of "Gossip Girl" on Tuesday (March 6)

Adding to season five, the co-stars were both well-dressed as they slipped into character with the Blair Waldorf babee wearing a yellow dress coat while the Chuck Bass stud looked suave in a pin-stripe suit.

The duo took on back-to-back filming dates for "Gossip Girl," as they were spotted stylishly taping the series on Monday, as well.

To check out the pictures of Meester and Westwick teamed up the previous day, click here!